全文获取类型
收费全文 | 1036篇 |
免费 | 183篇 |
国内免费 | 108篇 |
专业分类
化学 | 260篇 |
晶体学 | 17篇 |
力学 | 335篇 |
综合类 | 15篇 |
数学 | 309篇 |
物理学 | 391篇 |
出版年
2024年 | 2篇 |
2023年 | 11篇 |
2022年 | 19篇 |
2021年 | 25篇 |
2020年 | 36篇 |
2019年 | 28篇 |
2018年 | 21篇 |
2017年 | 36篇 |
2016年 | 35篇 |
2015年 | 31篇 |
2014年 | 57篇 |
2013年 | 88篇 |
2012年 | 59篇 |
2011年 | 76篇 |
2010年 | 46篇 |
2009年 | 64篇 |
2008年 | 52篇 |
2007年 | 68篇 |
2006年 | 65篇 |
2005年 | 59篇 |
2004年 | 61篇 |
2003年 | 43篇 |
2002年 | 37篇 |
2001年 | 42篇 |
2000年 | 35篇 |
1999年 | 27篇 |
1998年 | 26篇 |
1997年 | 19篇 |
1996年 | 29篇 |
1995年 | 18篇 |
1994年 | 17篇 |
1993年 | 13篇 |
1992年 | 13篇 |
1991年 | 19篇 |
1990年 | 9篇 |
1989年 | 9篇 |
1988年 | 7篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有1327条查询结果,搜索用时 15 毫秒
1.
Applied Mathematics and Mechanics - Mechanical models of residually stressed fibre-reinforced solids, which do not resist bending, have been developed in the literature. However, in some residually... 相似文献
2.
Dr. Si-Yong Qin Yan Jiang Dr. Han Sun Han Liu Prof. Ai-Qing Zhang Prof. Xinxiang Lei 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(39):17245-17251
Residual dipolar coupling (RDC), a robust anisotropic NMR parameter for structural elucidation of organic molecules, is only accessible in an anisotropic environment. Herein, we introduce a novel alignment medium based on the molecular self-assembly of oligopeptide amphiphile (OPA). This medium is compatible with different intermediate and polar solvent systems, such as CD3OD, [D6]DMSO, and D2O. The preparation of the OPA-based medium is simple and rapid, while only very weak background signals were observed from OPAs. Furthermore, we show that the purity of OPA has only a minor influence on the quality of the RDC data. These advantages allow RDC measurements of organic molecules with different polarities and solubilities with high efficiency and accuracy. 相似文献
3.
高能重带电粒子能直接穿透靶原子核外电子层,与原子核发生直接碰撞,发生散裂反应,产生一系列具有放射性的剩余产物核.重带电粒子诱发靶材放射性剩余核与辐射防护和人员安全有着密切联系,当前,大部分剩余核产额主要依靠蒙特卡罗粒子输运程序进行模拟计算,其准确程度亟需通过实验测量进行准确评估.本文利用能量为80.5 MeV/u的(12)^C6+粒子对薄铜靶开展了辐照实验与伽玛射线测量,结合伽玛谱学分析方法,得出了辐照产生的18种放射性剩余产物的初始活度和产生截面值,并与PHITS模拟结果进行对比.结果表明,PHITS模拟程序对放射性剩余核种类的估计具有较高可靠性,在其绝对产额方面,与实验测量仍具有较大偏差. 相似文献
4.
5.
针对有机合成过程中碳及碳化物的残余,传统方法中普遍使用除碳的工艺,而很少有文章针对非晶碳的结构和形貌进行表征。为此,本文采用高尿素含量的前驱盐体系,通过在氮气保护气氛中煅烧获得AlN粉体。采用X射线衍射分析、红外和拉曼光谱分析、扫描电子显微镜和透射电子显微镜对850~1 500 ℃温度范围内煅烧获得产物的结构和形貌进行表征,对AlN合成过程中含碳产物结构形貌的变化,以及AlN和含碳产物之间相互的依存生长关系进行分析。结果表明,AlN生长的过程中伴随着无定形碳的石墨化转变,AlN颗粒的形貌也受含碳残余产物形貌的影响而出现有规律的变化。 相似文献
6.
Leandro F. Gil‐Silva Raquel Santamaría‐Fernández Prof. Dr. Armando Navarro‐Vázquez Prof. Roberto R. Gil 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(2):472-476
A new DMSO‐compatible aligning gel based on cross‐linked poly(2‐hydroxylethyl methacrylate) (poly‐HEMA) has been developed. Due to a significant difference in bulk magnetic susceptibility between the DMSO inside and outside the gel, it is possible to simultaneously collect isotropic and anisotropic NMR data, such as residual dipolar couplings (RDC), in the same NMR tube. RDC‐assisted structural analysis of menthol and the alkaloid retrorsine is reported as proof of concept. 相似文献
7.
8.
对于呈现自相关和波动族聚性并存的受控过程,通常采用残差控制图对其进行监控。但异常点的存在会对自相关或波动族聚性模型的拟合产生重要影响,使得基于该模型的残差并非独立同分布导致常规残差控制图监控失效。为解决这类问题,本文提出稳健残差控制图。即建立稳健的ARMA模型解决自相关问题从而得到无自相关的残差序列,用稳健的GARCH模型来构建控制图的上下限。模拟和实证研究表明,本文提出的稳健残差控制图具有很好的抗异常点能力并能更好的对金融时间序列的异常现象进行监控。 相似文献
9.
Residual stress is the stress present in the unloaded equilibrium configuration of a body. Because residual stresses can significantly affect the mechanical behavior of a component, the measurement of these stresses and the prediction of their effect on mechanical behavior are important objectives in many engineering problems. Common methods for the measurement of residual stresses include various destructive experiments in which the body is cut to relieve the residual stress. The resulting strain is measured and used to approximate the original residual stress in the intact body. In order to predict the mechanical behavior of a residually stressed body, a constitutive model is required that includes the influence of the residual stress.In this paper we present a method by which the data obtained from standard destructive experiments can be used to derive constitutive equations that describe the mechanical behavior of elastic residually stressed bodies. The derivation is based on the idea that for each infinitesimal neighborhood in a residually stressed body, there exists a corresponding stress free configuration. We refer to this stress free configuration as the virtual configuration of the infinitesimal neighborhood. The derivation requires that the constitutive equation for the stress free material be known and invertible; it is used to relate the residual stress to the deformation of the virtual configuration into the residually stressed configuration. Although the concept of the virtual configuration is central to the derivation, the geometry of this configuration need not be determined explicitly, and it need not be achievable experimentally, in order to construct the constitutive equation for the residually stressed body.The general mathematical forms of constitutive equations valid for residually stressed elastic materials have been derived previously for a number of cases. These general forms contain numerous unknown material-response functions or material constants that must be determined experimentally. In contrast, the method presented here results in a constitutive equation that is an explicit function of residual stress and includes only the material parameters required to describe the stress free material.After presenting the method for the derivation of constitutive equations, we explore the relationship between destructive experiments and the theory used in the derivation. Specifically, we discuss the use of the theory to improve the design of destructive experiments, and the use of destructive experiments to obtain the data required to construct the constitutive equation for a particular material. 相似文献
10.
本文在建立了受损构件和受损结构体系残余承载力模糊评估理论的基础上,以这两个方法的主要原理为思想,设计了一智能评估专家系统。作者在文中着重给出了知识库、推理机和系统流程图的构造,并结合实例,说明了该专家系统的应用。 相似文献